QUESTION IMAGE
Question
write the balanced equation. write the ionic equation and net ionic equations for the following reaction. (6marks)
part a
a. balance equation (predict the products and their state of matter)
bi(no₃)₃(aq) + naoh(aq) ------->
b. ionic equation
c. net ionic equation
part b
using lewis diagrams illustrate the formations of bond(s) between sodium na and phosphorous p. name this compound (4 marks)
Part A
a. Balance equation (predict the products and their state of matter)
Step 1: Predict products
Bismuth(III) nitrate ($\ce{Bi(NO_{3})_{3}}$) reacts with sodium hydroxide ($\ce{NaOH}$) in a double - displacement reaction. The products are bismuth(III) hydroxide ($\ce{Bi(OH)_{3}}$) and sodium nitrate ($\ce{NaNO_{3}}$). Bismuth(III) hydroxide is insoluble in water (so it is a solid, $s$), and sodium nitrate is soluble (so it is in aqueous state, $aq$).
Step 2: Balance the equation
- For the nitrate ions ($\ce{NO_{3}^-}$): There are 3 $\ce{NO_{3}^-}$ in $\ce{Bi(NO_{3})_{3}}$, so we need 3 $\ce{NaNO_{3}}$ on the product side. This means we need 3 $\ce{NaOH}$ on the reactant side to balance the sodium ions ($\ce{Na^+}$).
- For the hydroxide ions ($\ce{OH^-}$) and bismuth ions ($\ce{Bi^{3+}}$): 3 $\ce{OH^-}$ from 3 $\ce{NaOH}$ react with 1 $\ce{Bi^{3+}}$ from $\ce{Bi(NO_{3})_{3}}$ to form 1 $\ce{Bi(OH)_{3}}$. So the balanced equation is $\ce{Bi(NO_{3})_{3}(aq) + 3NaOH(aq) -> Bi(OH)_{3}(s) + 3NaNO_{3}(aq)}$.
b. Ionic equation
Step 1: Dissociate soluble compounds
- $\ce{Bi(NO_{3})_{3}(aq)}$ dissociates into $\ce{Bi^{3+}(aq)}$ and $\ce{3NO_{3}^-(aq)}$ because it is soluble in water.
- $\ce{NaOH(aq)}$ dissociates into $\ce{Na^+(aq)}$ and $\ce{OH^-(aq)}$, and since we have 3 moles of $\ce{NaOH}$, we have $\ce{3Na^+(aq)}$ and $\ce{3OH^-(aq)}$.
- $\ce{NaNO_{3}(aq)}$ dissociates into $\ce{Na^+(aq)}$ and $\ce{NO_{3}^-(aq)}$, and with 3 moles of $\ce{NaNO_{3}}$, we have $\ce{3Na^+(aq)}$ and $\ce{3NO_{3}^-(aq)}$.
- $\ce{Bi(OH)_{3}(s)}$ does not dissociate as it is a solid.
Step 2: Write the ionic equation
Substitute the dissociated ions into the balanced molecular equation: $\ce{Bi^{3+}(aq) + 3NO_{3}^-(aq) + 3Na^+(aq) + 3OH^-(aq) -> Bi(OH)_{3}(s) + 3Na^+(aq) + 3NO_{3}^-(aq)}$.
c. Net ionic equation
Step 1: Identify spectator ions
Spectator ions are ions that appear on both sides of the ionic equation and do not participate in the chemical reaction. In the ionic equation $\ce{Bi^{3+}(aq) + 3NO_{3}^-(aq) + 3Na^+(aq) + 3OH^-(aq) -> Bi(OH)_{3}(s) + 3Na^+(aq) + 3NO_{3}^-(aq)}$, the $\ce{Na^+(aq)}$ and $\ce{NO_{3}^-(aq)}$ ions are spectator ions.
Step 2: Remove spectator ions
After removing the spectator ions ($\ce{Na^+}$ and $\ce{NO_{3}^-}$) from the ionic equation, we get the net ionic equation: $\ce{Bi^{3+}(aq) + 3OH^-(aq) -> Bi(OH)_{3}(s)}$.
Part B
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$\ce{Bi(NO_{3})_{3}(aq) + 3NaOH(aq) -> Bi(OH)_{3}(s) + 3NaNO_{3}(aq)}$