QUESTION IMAGE
Question
- use the solubility rules to identify the precipitate in the reaction. aqueous solutions of potassium hydroxide and cobalt(iii) nitrate are mixed.
here are the solubility rules.
- alkali metal (li+, na+, k+, etc) and ammonium (nh4+) salts are generally soluble. exceptions include li2co3 and li3po4.
- nitrate (no3-) salts are generally soluble.
- silver (ag+) and lead (pb2+) salts are generally insoluble.
- halide (cl-, br-, and i-) salts are generally soluble. exceptions include pb2+, ag+, hg2^2+.
- carbonate (co3^2-), phosphate (po4^3-), and hydroxide (oh-) salts are generally insoluble.
- sulfate (so4^2-) salts are generally soluble. exceptions include caso4, srso4, baso4, pbso4, and ag2so4.
koh
kno3
co(no3)3
co(oh)3
Step1: Write the reaction equation
When potassium hydroxide ($\ce{KOH}$) and cobalt(III) nitrate ($\ce{Co(NO_{3})_{3}}$) are mixed, the double - replacement reaction occurs: $\ce{3KOH(aq) + Co(NO_{3})_{3}(aq)\xlongequal{}3KNO_{3}(aq) + Co(OH)_{3}(s)}$ (we assume the precipitate is one of the products, and we will check solubility for each product).
Step2: Analyze solubility of $\ce{KNO_{3}}$
According to solubility rule 1 (alkali metal salts are generally soluble) and rule 2 (nitrate salts are generally soluble), $\ce{KNO_{3}}$ (containing $\ce{K^{+}}$ and $\ce{NO^{-}_{3}}$) is soluble in water.
Step3: Analyze solubility of $\ce{Co(OH)_{3}}$
$\ce{Co(OH)_{3}}$ is a hydroxide salt. According to solubility rule 5, hydroxide ($\ce{OH^{-}}$) salts are generally insoluble. Cobalt(III) ion ($\ce{Co^{3+}}$) does not fall into the exception categories for hydroxide solubility, so $\ce{Co(OH)_{3}}$ is insoluble and will form a precipitate.
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$\ce{Co(OH)_{3}}$