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Question
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the equilibrium constant, ( k_c ), for the following reaction is 10.5 at 350 k.
( 2ch_2cl_2(g)
ightleftharpoons ch_4(g)+ccl_4(g) )
assuming that you start with only ( ch_2cl_2 ), describe the relative abundance of each species present at equilibrium.
ch₄
ccl₄
ch₂cl₂
lower
higher
cant tell
clear all
Step1: Write the equilibrium constant expression
For the reaction \(2CH_{2}Cl_{2}(g)
ightleftharpoons CH_{4}(g)+CCl_{4}(g)\), the equilibrium constant \(K_{c}=\frac{[CH_{4}][CCl_{4}]}{[CH_{2}Cl_{2}]^{2}}\)
Step2: Analyze the value of \(K_{c}\)
Given \(K_{c} = 10.5\) (a value greater than \(1\)). When \(K_{c}>1\), the numerator \([CH_{4}][CCl_{4}]\) is greater than the denominator \([CH_{2}Cl_{2}]^{2}\) at equilibrium.
Since the stoichiometric coefficients of \(CH_{4}\) and \(CCl_{4}\) are \(1\) (equal), and we start with only \(CH_{2}Cl_{2}\), at equilibrium \([CH_{4}]=[CCl_{4}]\).
Let \([CH_{4}]=[CCl_{4}]=x\) and \([CH_{2}Cl_{2}]=y\). Then \(K_{c}=\frac{x\times x}{y^{2}}=\frac{x^{2}}{y^{2}} = 10.5\), so \(x>y\)
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\([CH_{4}]\): Higher, \([CCl_{4}]\): Higher, \([CH_{2}Cl_{2}]\): Lower