QUESTION IMAGE
Question
h₂o + h₂o ↔ h₃o⁺¹ + oh⁻¹
h₃o⁺¹ oh⁻¹
k_w = ------------- = h₃o⁺¹ oh⁻¹ = (1 × 10⁻⁷)² = 1 × 10⁻¹⁴
h₂o²
the inverse logarithm, or -log, of h₃o⁺¹ oh⁻¹ = 10⁻¹⁴ is ph + poh = 14
- what happens to the h₃o⁺¹ when acid is added to neutral water ?
the h₃o⁺¹ goes 1
- what happens to the ph when acid is added to neutral water ?
an example of an increased h₃o⁺¹ is h₃o⁺¹ = 1 × 10⁻⁶ and ph = -log10⁻⁶ = 6
thus, adding acid makes the ph go 2
- what happens to the oh⁻¹ when acid is added to neutral water ?
in the equation h₃o⁺¹ oh⁻¹ = 10⁻¹⁴, when h₃o⁺¹ increases, the oh⁻¹ goes 3
- what happens to the poh when acid is added to neutral water ?
when oh⁻¹ decreases, the poh goes 4 since the poh = -logoh⁻¹
this can also be seen using ph + poh = 14
- what happens to the k_w when acid is added to neutral water ?
Sub - question 1
Step1: Recall acid - water reaction
Acids dissociate in water to give \(H_3O^+\) ions. For example, \(HCl + H_2O
ightarrow H_3O^++Cl^-\).
Step2: Analyze \( [H_3O^{+1}] \) change
When acid is added to neutral water, the acid provides more \(H_3O^+\) ions. So the concentration of \(H_3O^+\) (i.e., \( [H_3O^{+1}] \)) increases.
Step1: Recall pH formula
The formula for pH is \(pH =-\log[H_3O^+]\).
Step2: Analyze pH change with \( [H_3O^+] \)
From sub - question 1, we know that \( [H_3O^+] \) increases when acid is added. Since the logarithm function \(y =-\log(x)\) is a decreasing function (as \(x\) increases, \(y\) decreases), when \( [H_3O^+] \) increases, the pH value (which is \( -\log[H_3O^+] \)) decreases. For example, if \( [H_3O^+]=1\times10^{-7}\) (neutral water), \(pH = 7\); if \( [H_3O^+]=1\times10^{-6}\), \(pH=-\log(1\times10^{-6}) = 6\), which is a decrease from 7.
Step1: Recall \(K_w\) expression
We know that \(K_w=[H_3O^+][OH^-]=1\times10^{-14}\) (at \(25^{\circ}C\)).
Step2: Analyze \( [OH^{-1}] \) change
From sub - question 1, \( [H_3O^+] \) increases. Since \(K_w\) is a constant (at a given temperature), if \( [H_3O^+] \) increases, then \( [OH^-]=\frac{K_w}{[H_3O^+]}\) must decrease (because \(K_w\) is fixed and the numerator is constant while the denominator increases).
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