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Question
- how is the molar volume of a gas defined at stp?
a. 22.4 liters per mole
b. 18.02 liters per mole
c. 6.022 × 10²³ liters per mole
d. 1 liter per mole
Step1: Recall the definition of molar volume at STP
The molar volume of a gas at Standard Temperature and Pressure (STP: \(T = 273\space K\), \(P= 1\space atm\)) is defined as the volume occupied by one mole of an ideal gas.
Step2: Use the ideal gas law \(PV=nRT\)
At STP, \(P = 1\space atm\), \(n = 1\space mol\), \(R=0.0821\space L\cdot atm/(mol\cdot K)\), \(T = 273\space K\). Substitute into \(V=\frac{nRT}{P}\).
$$V=\frac{1\space mol\times0.0821\space L\cdot atm/(mol\cdot K)\times273\space K}{1\space atm}=22.4\space L/mol$$
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a. 22.4 liters per mole