QUESTION IMAGE
Question
- (q-2,6b) qaysi alkin gidratlansa, etanal ch₂cho hosil boladi?
a) pentin-1 b) propin
c) butin-2 d) asetilen
- (q-2,6b) qaysi modda suv bilan reaktsiyaga kirishib,keton hosil qiladi?
- atsetilen 2) butin-1 3) butin-2
a) 1,3 b) 2,3
c) 1,2 d) 1
- (q-2,6b) quyidagi uglevodorodni sistematik nomenklatura boyicha nomlang:
ch₂=ch-ch₂-ch(ch₃)-ch₃
a) 3-metilpenten-1 b) 2-metilpenten-4
c) 4-metilpenten-1 d) 4-metilbuten-1
- (q-2,6b) quyidagi moddalardan qaysi biri geometrik (sis-trans/z va e) izomeriyaga
ega bola olmaydi?
a) buten-2 b) 1,2-dixloroeten
c) 1-xloropropen d) penten-1
- (q-2,6b) 2-metilbuten-1 toliq gidrogenlansa, hosil bolgan alkanda nechta birlamchi uglerod
atomi mavjud boladi?
a) 1 b) 3
c) 2 d) 4
- (q-2,6b) benzol yadrosiga yon zanjirlar 1 va 2 holatda joylashsa bu qanday nomlanadi?
a) orto b) para
c) meta d) izo
Question 25
To determine which alkyne forms ethanal ($\ce{CH3CHO}$) upon hydration, we analyze the hydration of alkynes. Hydration of alkynes follows Markovnikov's rule (except for acetylene, which gives acetaldehyde). Propene (alkene) or propyne? Wait, the question is about alkyne. Wait, hydration of propyne: Propyne ($\ce{CH3C\equiv CH}$) upon hydration (with $\ce{H2O}$, $\ce{HgSO4}$, $\ce{H2SO4}$) undergoes keto - enol tautomerism. The enol form (from propyne hydration) tautomerizes to acetone? Wait, no, maybe I made a mistake. Wait, acetylene ($\ce{HC\equiv CH}$) hydration gives acetaldehyde (ethanal). Wait, the options: A) Pent - 1 - yne, B) Propyne, C) But - 2 - yne, D) Acetylene (Asetilen). Wait, hydration of acetylene: $\ce{HC\equiv CH + H2O ->[\ce{HgSO4},\ce{H2SO4}] CH2=CHOH}$ (enol), which tautomerizes to $\ce{CH3CHO}$ (ethanal). So the alkyne is acetylene (Asetilen). But let's check the options. Wait, the question is "Qaysi alkin gidratlansa, etanal $\ce{CH3CHO}$ hosil bo'ladi?" (Which alkyne, when hydrated, forms ethanal?). So acetylene (D) is the answer? Wait, no, maybe propyne? Wait, no, let's re - recall. The hydration of alkynes: terminal alkynes (except acetylene) give methyl ketones, acetylene gives acetaldehyde. So acetylene (D) is the correct answer.
We need to find which substance reacts with water to form a ketone. Let's analyze each substance:
- Asetilen (Acetylene): Hydration of acetylene gives acetaldehyde (an aldehyde), not a ketone.
- But - 1 - yne: Hydration of but - 1 - yne (terminal alkyne) gives a methyl ketone? Wait, no, but - 1 - yne is a terminal alkyne. Wait, the reaction of alkynes with water (in the presence of $\ce{HgSO4}$ and $\ce{H2SO4}$) follows Markovnikov's addition. For non - terminal alkynes (internal alkynes) like but - 2 - yne: $\ce{CH3C\equiv CCH3 + H2O ->[\ce{HgSO4},\ce{H2SO4}] CH3COCH2CH3}$ (a ketone). For terminal alkynes (like acetylene, but - 1 - yne), acetylene gives acetaldehyde (aldehyde), but - 1 - yne gives a ketone? Wait, no, the general rule is that terminal alkynes (except acetylene) give methyl ketones, acetylene gives acetaldehyde. Wait, let's re - check:
- Asetilen (1): gives aldehyde (not ketone).
- Butin - 1 (2): terminal alkyne, hydration gives a ketone? Wait, no, the formula of but - 1 - yne is $\ce{CH3CH2C\equiv CH}$. Hydration: $\ce{CH3CH2C\equiv CH + H2O ->[\ce{HgSO4},\ce{H2SO4}] CH3CH2COCH3}$ (a ketone)? Wait, maybe I was wrong earlier. And butin - 2 (3) is an internal alkyne ($\ce{CH3C\equiv CCH3}$), hydration gives $\ce{CH3COCH2CH3}$ (ketone). So substances 1 (asetilen) gives aldehyde, 2 (butin - 1) gives ketone, 3 (butin - 2) gives ketone. Wait, the options: A) 1,3; B) 2,3; C) 1,2; D) 1. So 2 (butin - 1) and 3 (butin - 2) react with water to form ketones. So the correct option is B.
To name the hydrocarbon $\ce{CH2=CH - CH2 - CH(CH3)-CH3}$ using systematic nomenclature, we follow IUPAC rules for alkenes:
- Find the longest carbon chain with the double bond: The longest chain has 5 carbon atoms (pentene).
- Number the chain to give the double bond the lowest number: The double bond is at carbon - 1 (since $\ce{CH2=}$ is at the start).
- Identify and number the substituents: There is a methyl group at carbon - 3 (since the carbon chain is numbered as 1: $\ce{CH2=}$, 2: $\ce{CH - }$, 3: $\ce{CH2 - }$, 4: $\ce{CH(CH3)-}$, 5: $\ce{CH3}$? Wait, no, let's number the chain correctly. The structure is $\ce{CH2=CH - CH2 - CH(CH3)-CH3}$. Let's number from the end closest to the double bond. The double bond is between C1 and C2. Then the carbon atoms are: C1: $\ce{CH2=}$, C2: $\ce{CH - }$, C3: $\ce{CH2 - }$, C4: $\ce{CH(CH3)-}$, C5: $\ce{CH3}$. So the substituent (methyl) is at C3. So the name is 3 - metilpenten - 1 (3 - methylpent - 1 - ene).
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D. Asetilen