QUESTION IMAGE
Question
sch4u
structure and
properties of matter
assignment
- complete the table below by providing a set of quantum numbers for the last four
electrons in an phosphorus atom. 4
Step1: Determine the electron configuration of phosphorus
Phosphorus has an atomic number of 15. Its electron configuration is \(1s^{2}2s^{2}2p^{6}3s^{2}3p^{3}\). The last four electrons are in the \(3s^{2}3p^{2}\) sub - shells.
Step2: Recall the rules for quantum numbers
- Principal quantum number (\(n\)): For the \(3s\) and \(3p\) sub - shells, \(n = 3\).
- Orbital shape quantum number (\(l\)): For \(s\) sub - shell \(l=0\), for \(p\) sub - shell \(l = 1\).
- Magnetic quantum number (\(m_{l}\)): For \(l = 0\), \(m_{l}=0\); for \(l = 1\), \(m_{l}=- 1,0,1\).
- Spin quantum number (\(m_{s}\)): Can be \(+\frac{1}{2}\) or \(-\frac{1}{2}\)
Step3: Assign quantum numbers for each electron
- Electron 1 (\(3s^{1}\)): \(n = 3\), \(l = 0\), \(m_{l}=0\), \(m_{s}=+\frac{1}{2}\)
- Electron 2 (\(3s^{2}\)): \(n = 3\), \(l = 0\), \(m_{l}=0\), \(m_{s}=-\frac{1}{2}\)
- Electron 3 (\(3p^{1}\)): \(n = 3\), \(l = 1\), \(m_{l}=-1\), \(m_{s}=+\frac{1}{2}\)
- Electron 4 (\(3p^{2}\)): \(n = 3\), \(l = 1\), \(m_{l}=0\), \(m_{s}=+\frac{1}{2}\)
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| e- | Principle quantum number | Orbital Shape quantum numbers | Magnetic quantum number | Spin quantum number |
|---|---|---|---|---|
| 2 | 3 | 0 | 0 | \(-\frac{1}{2}\) |
| 3 | 3 | 1 | - 1 | \(+\frac{1}{2}\) |
| 4 | 3 | 1 | 0 | \(+\frac{1}{2}\) |