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sch4u structure and properties of matter assignment 1. complete the tab…

Question

sch4u
structure and
properties of matter
assignment

  1. complete the table below by providing a set of quantum numbers for the last four

electrons in an phosphorus atom. 4

Explanation:

Step1: Determine the electron configuration of phosphorus

Phosphorus has an atomic number of 15. Its electron configuration is \(1s^{2}2s^{2}2p^{6}3s^{2}3p^{3}\). The last four electrons are in the \(3s^{2}3p^{2}\) sub - shells.

Step2: Recall the rules for quantum numbers

  • Principal quantum number (\(n\)): For the \(3s\) and \(3p\) sub - shells, \(n = 3\).
  • Orbital shape quantum number (\(l\)): For \(s\) sub - shell \(l=0\), for \(p\) sub - shell \(l = 1\).
  • Magnetic quantum number (\(m_{l}\)): For \(l = 0\), \(m_{l}=0\); for \(l = 1\), \(m_{l}=- 1,0,1\).
  • Spin quantum number (\(m_{s}\)): Can be \(+\frac{1}{2}\) or \(-\frac{1}{2}\)

Step3: Assign quantum numbers for each electron

  • Electron 1 (\(3s^{1}\)): \(n = 3\), \(l = 0\), \(m_{l}=0\), \(m_{s}=+\frac{1}{2}\)
  • Electron 2 (\(3s^{2}\)): \(n = 3\), \(l = 0\), \(m_{l}=0\), \(m_{s}=-\frac{1}{2}\)
  • Electron 3 (\(3p^{1}\)): \(n = 3\), \(l = 1\), \(m_{l}=-1\), \(m_{s}=+\frac{1}{2}\)
  • Electron 4 (\(3p^{2}\)): \(n = 3\), \(l = 1\), \(m_{l}=0\), \(m_{s}=+\frac{1}{2}\)

Answer:

e-Principle quantum numberOrbital Shape quantum numbersMagnetic quantum numberSpin quantum number
2300\(-\frac{1}{2}\)
331- 1\(+\frac{1}{2}\)
4310\(+\frac{1}{2}\)