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question 4 indicate the most important type of intermolecular attractio…

Question

question 4
indicate the most important type of intermolecular attraction responsible for solvation in each of the following solutions.

solutionintermolecular attraction
toluene (c₇h₈) in benzene (c₆h₆)--
cacl₂ in water--

options: dipole-dipole, hydrogen bonding, ion-dipole, dispersion
question 5
the henry’s law constant for o₂ is... of oxygen would be dissolved in a 40-l aquarium at 25 °c, assuming an...

Explanation:

Brief Explanations
  • Ethanol (\(C_2H_5OH\)) has an -OH group. Water (\(H_2O\)) also has -OH groups. Hydrogen bonding occurs when a hydrogen atom is bonded to a highly electronegative atom (such as O, N, or F) and interacts with another electronegative atom. In the case of ethanol in water, the -OH of ethanol and -OH of water can form hydrogen bonds.
  • Toluene (\(C_7H_8\)) and benzene (\(C_6H_6\)) are both non - polar hydrocarbons. The most significant intermolecular force in non - polar substances is London dispersion forces (dispersion forces). These forces arise from temporary dipoles caused by the motion of electrons in the molecules.
  • \(CaCl_2\) is an ionic compound (\(Ca^{2 + }\) and \(2Cl^-\)). Water (\(H_2O\)) is a polar molecule (has a dipole moment). Ion - dipole forces occur between ions (from the ionic compound) and polar molecules (like water). The positive ions (\(Ca^{2+}\)) are attracted to the negative end of the water dipole (oxygen - rich end), and the negative ions (\(Cl^-\)) are attracted to the positive end of the water dipole (hydrogen - rich end).

Answer:

  • Ethanol (\(C_2H_5OH\)) in water: hydrogen bonding
  • Toluene (\(C_7H_8\)) in benzene (\(C_6H_6\)): dispersion
  • \(CaCl_2\) in water: ion - dipole