QUESTION IMAGE
Question
- use the solubility rules to identify the precipitate in the reaction. aqueous solutions of potassium hydroxide and cobalt(iii) nitrate are mixed.
here are the solubility rules.
- alkali metal (li⁺, na⁺, k⁺, etc) and ammonium (nh₄⁺) salts are generally soluble. exceptions include li₂co₃ and li₃po₄.
- nitrate (no₃⁻) salts are generally soluble.
- silver (ag⁺) and lead (pb²⁺) salts are generally insoluble.
- halide (cl⁻, br⁻, and i⁻) salts are generally soluble. exceptions include pb²⁺, ag⁺, hg₂²⁺.
- carbonate (co₃²⁻), phosphate (po₄³⁻), and hydroxide (oh⁻) salts are generally insoluble.
- sulfate (so₄²⁻) salts are generally soluble. exceptions include caso₄, srso₄, baso₄, pbso₄, and ag₂so₄.
koh
kno₃
co(no₃)₃
co(oh)₃
Step1: Write the reaction equation
The reaction between potassium hydroxide ($\ce{KOH}$) and cobalt(III) nitrate ($\ce{Co(NO_{3})_{3}}$) is a double - displacement reaction. The chemical equation is: $\ce{3KOH(aq) + Co(NO_{3})_{3}(aq)\xlongequal{}Co(OH)_{3}(s) + 3KNO_{3}(aq)}$
Step2: Analyze solubility of products using solubility rules
- For $\ce{KNO_{3}}$: According to solubility rule 1 (alkali metal salts are generally soluble) and rule 2 (nitrate salts are generally soluble), $\ce{KNO_{3}}$ is soluble in water.
- For $\ce{Co(OH)_{3}}$: According to solubility rule 5, hydroxide ($\ce{OH^{-}}$) salts are generally insoluble. Cobalt(III) hydroxide does not fall into any of the exception categories for hydroxide salts, so it is insoluble and will form a precipitate.
- $\ce{KOH}$ and $\ce{Co(NO_{3})_{3}}$ are reactants and are in aqueous solution initially, so they are not precipitates.
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$\ce{Co(OH)_{3}}$