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Question
electronegativity is a calculated value for each element and is based upon the bonding behavior of each element. en is the ability of an element to pull electrons towards itself in a bond. depending upon the difference in electronegativity, \\( \delta \mathrm{en} \\), there may be partial charges assigned. the element with higher electronegativity is assigned a partial negative charge, \\( \delta - \\). the element with the lower en is assigned a partial positive charge, \\( \delta + \\). if the \\( \delta \mathrm{en} \\) is insignificant, < 0.5, the bond is called a nonpolar covalent bond, the electrons are shared fairly evenly, and en does not significantly affect the properties of the molecule. if the \\( \delta \mathrm{en} \\) is between 0.5 and 1.7, the bond is called a polar covalent bond, the electrons are not shared equally, partial charges are assigned to represent a dipole, and this may cause the molecule to behave like a magnet. if the dipoles cancel the molecule is nonpolar. if the dipoles dont cancel, the molecule is polar and acts like a magnet. if the \\( \delta \mathrm{en} \\) is > 1.7, the bond is called ionic, the electrons are very unequally shared, and the individual ions act like strong magnets. consider fluorine, \\( \mathrm{f}_{2} \\). the en for fluorine is 1. the \\( \delta \mathrm{en} \\) for the bond between f and f is 2. this means that the bonding electrons are shared evenly between the f and the f atoms. thus, the bond in \\( \mathrm{f}_{2} \\) is a 3 bond. also, since \\( \mathrm{f}_{2} \\) has no 4 bonds, there is no dipole in the molecule and \\( \mathrm{f}_{2} \\) is a
Step1: Determine electronegativity of fluorine
Fluorine has the highest electronegativity value. From the Pauling scale, the electronegativity of fluorine (\(F\)) is \(4.0\).
Step2: Calculate \(\Delta EN\) for \(F - F\) bond
The formula for \(\Delta EN\) is \(\Delta EN=\vert EN_1 - EN_2\vert\). For \(F - F\) bond, \(EN_1 = EN_2=4.0\). So \(\Delta EN=\vert4.0 - 4.0\vert = 0\).
Step3: Classify the bond type
Since \(\Delta EN = 0<0.5\), according to the given criteria, the bond is non - polar covalent.
Step4: Analyze dipole formation
Since the bond in \(F_2\) is non - polar covalent (no difference in electronegativity between the two \(F\) atoms), there are no polar bonds.
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- \(4.0\)
- \(0\)
- non - polar covalent
- polar