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Question
acetic acid (hc₂h₃o₂) is the primary component of vinegar. it is produced along with water (h₂o) when methanol (ch₃oh) reacts with carbon dioxide (co₂) and hydrogen gas (h₂). which chemical equation accurately represents this reaction? ch₃oh (l) + co₂ (g) + h₂ (g) → hc₂h₃o₂ (l) + h₂o (l) ch₃oh (l) + 3co₂ (g) + 5h₂ (g) → 3hc₂h₃o₂ (l) + h₂o (l) 2ch₃oh (l) + 2co₂ (g) + h₂ (g) → 2hc₂h₃o₂ (l) + h₂o (l) 2ch₃oh (l) + co₂ (g) + 2h₂ (g) → 2hc₂h₃o₂ (l) + 2h₂o (l)
Step1: Count atoms on both sides
For carbon (\(C\)):
- In \(2CH_{3}OH\), there are \(2\times1 = 2\) \(C\) atoms.
- In \(CO_{2}\), there is \(1\) \(C\) atom. So total \(C\) atoms on reactant side: \(2 + 1=3\).
- In \(2HC_{2}H_{3}O_{2}\), there are \(2\times2 = 4\) \(C\) atoms. This is incorrect.
For hydrogen (\(H\)):
- In \(2CH_{3}OH\), there are \(2\times4 = 8\) \(H\) atoms.
- In \(2H_{2}\), there are \(2\times2 = 4\) \(H\) atoms. So total \(H\) atoms on reactant side: \(8+4 = 12\).
- In \(2HC_{2}H_{3}O_{2}\), there are \(2\times4 = 8\) \(H\) atoms. In \(2H_{2}O\), there are \(2\times2 = 4\) \(H\) atoms. Total \(H\) atoms on product side: \(8 + 4=12\).
For oxygen (\(O\)):
- In \(2CH_{3}OH\), there are \(2\times1 = 2\) \(O\) atoms.
- In \(CO_{2}\), there are \(2\) \(O\) atoms. So total \(O\) atoms on reactant side: \(2+2 = 4\).
- In \(2HC_{2}H_{3}O_{2}\), there are \(2\times2 = 4\) \(O\) atoms. In \(2H_{2}O\), there are \(2\times1 = 2\) \(O\) atoms. Total \(O\) atoms on product side: \(4+2 = 6\). This is incorrect.
Step2: Check another option
For \(2CH_{3}OH(l)+2CO_{2}(g)+H_{2}(g)\to2HC_{2}H_{3}O_{2}(l)+H_{2}O(l)\)
- Carbon (\(C\)):
- Reactant side: In \(2CH_{3}OH\), \(2\times1 = 2\) \(C\) atoms. In \(2CO_{2}\), \(2\times1 = 2\) \(C\) atoms. Total \(C\) atoms: \(2 + 2=4\).
- Product side: In \(2HC_{2}H_{3}O_{2}\), \(2\times2 = 4\) \(C\) atoms.
- Hydrogen (\(H\)):
- Reactant side: In \(2CH_{3}OH\), \(2\times4 = 8\) \(H\) atoms. In \(H_{2}\), \(2\) \(H\) atoms. Total \(H\) atoms: \(8+2 = 10\).
- Product side: In \(2HC_{2}H_{3}O_{2}\), \(2\times4 = 8\) \(H\) atoms. In \(H_{2}O\), \(2\) \(H\) atoms. Total \(H\) atoms: \(8 + 2=10\).
- Oxygen (\(O\)):
- Reactant side: In \(2CH_{3}OH\), \(2\times1 = 2\) \(O\) atoms. In \(2CO_{2}\), \(2\times2 = 4\) \(O\) atoms. Total \(O\) atoms: \(2+4 = 6\).
- Product side: In \(2HC_{2}H_{3}O_{2}\), \(2\times2 = 4\) \(O\) atoms. In \(H_{2}O\), \(1\) \(O\) atom. Total \(O\) atoms: \(4 + 1=5\). This is incorrect.
Step3: Check \(CH_{3}OH(l)+3CO_{2}(g)+5H_{2}(g)\to3HC_{2}H_{3}O_{2}(l)+H_{2}O(l)\)
- Carbon (\(C\)):
- Reactant side: In \(CH_{3}OH\), \(1\) \(C\) atom. In \(3CO_{2}\), \(3\times1 = 3\) \(C\) atoms. Total \(C\) atoms: \(1+3 = 4\).
- Product side: In \(3HC_{2}H_{3}O_{2}\), \(3\times2 = 6\) \(C\) atoms. This is incorrect.
Step4: Check \(CH_{3}OH(l)+CO_{2}(g)+H_{2}(g)\to HC_{2}H_{3}O_{2}(l)+H_{2}O(l)\)
- Carbon (\(C\)):
- Reactant side: In \(CH_{3}OH\), \(1\) \(C\) atom. In \(CO_{2}\), \(1\) \(C\) atom. Total \(C\) atoms: \(1 + 1=2\).
- Product side: In \(HC_{2}H_{3}O_{2}\), \(2\) \(C\) atoms.
- Hydrogen (\(H\)):
- Reactant side: In \(CH_{3}OH\), \(4\) \(H\) atoms. In \(H_{2}\), \(2\) \(H\) atoms. Total \(H\) atoms: \(4+2 = 6\).
- Product side: In \(HC_{2}H_{3}O_{2}\), \(4\) \(H\) atoms. In \(H_{2}O\), \(2\) \(H\) atoms. Total \(H\) atoms: \(4 + 2=6\).
- Oxygen (\(O\)):
- Reactant side: In \(CH_{3}OH\), \(1\) \(O\) atom. In \(CO_{2}\), \(2\) \(O\) atoms. Total \(O\) atoms: \(1+2 = 3\).
- Product side: In \(HC_{2}H_{3}O_{2}\), \(2\) \(O\) atoms. In \(H_{2}O\), \(1\) \(O\) atom. Total \(O\) atoms: \(2+1 = 3\).
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\(CH_{3}OH(l)+CO_{2}(g)+H_{2}(g)\to HC_{2}H_{3}O_{2}(l)+H_{2}O(l)\)