QUESTION IMAGE
Question
a. 1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 5s² 5d⁹
- the number of electrons in the valence shell of
the argon atom is:
a. 10.
b. 2.
c. 6.
d. 8.
- which of the following rules requires that each of
the p orbitals in the same principal energy level
receive one electron before any of them can have
two electrons?
a. hunds rule
b. the pauli exclusion principle
c. the aufbau principle
d. the quantum rule
- choose the orbital diagram which obeys hund’s
rule:
a.
b.
c.
d.
e.
Question 8
Step1: Recall Argon's Electron Configuration
Argon (Ar) has an atomic number of 18. Its electron configuration is \(1s^2 2s^2 2p^6 3s^2 3p^6\).
Step2: Identify Valence Shell
The valence shell is the outermost shell, which for argon is the \(n = 3\) shell (3s and 3p).
Step3: Calculate Valence Electrons
In the \(3s\) subshell, there are 2 electrons, and in the \(3p\) subshell, there are 6 electrons. So total valence electrons: \(2 + 6 = 8\).
Step1: Recall Electron Rules
- Hund's Rule: Electrons fill degenerate orbitals (same energy) singly with parallel spins before pairing. For p orbitals (three degenerate orbitals in a subshell), each gets one electron before pairing.
- Pauli Exclusion Principle: No two electrons in an atom have the same set of quantum numbers (max 2 electrons per orbital, opposite spins).
- Aufbau Principle: Electrons fill orbitals in order of increasing energy.
- "Quantum Rule" is not a standard electron - filling rule.
Step2: Match the Description
The description "each of the p orbitals in the same principal energy level receive one electron before any of them can have two electrons" matches Hund's Rule.
Step1: Recall Hund's Rule
Hund's Rule states that electrons fill degenerate orbitals (like 2p orbitals, which are degenerate) singly with parallel spins before pairing. Also, electrons in the same orbital have opposite spins (Pauli Exclusion), and orbitals are filled in order of increasing energy (Aufbau, but Hund's is about degenerate orbitals).
Step2: Analyze Each Option
- Option a: In 2p orbitals, there are both up and down spins in different orbitals, violating parallel spins for unpaired electrons.
- Option b: 2p orbitals are not filled singly first (only one orbital has electrons), violates Hund's Rule.
- Option c: The spins in 2p orbitals are not all parallel for unpaired electrons (has a down spin among up spins), violates Hund's Rule.
- Option d: Orbitals have more than two electrons (violates Pauli Exclusion) and does not follow Hund's Rule for filling.
- Option e: Wait, let's re - check. Wait, the correct one should have: 1s and 2s filled with two electrons (opposite spins), and 2p orbitals: first, each 2p orbital gets one electron with parallel spins. Let's look at the options again. Wait, maybe I mislabeled. Wait, the correct orbital diagram for Hund's rule: for 2p (three degenerate orbitals), electrons should fill each orbital singly with parallel spins before pairing. Let's check the original options again. Wait, maybe the correct one is the one where in 2p orbitals, the electrons are in separate orbitals with parallel spins. Wait, among the given options, let's re - evaluate:
Wait, the 2p subshell has three orbitals. Hund's rule says electrons fill each orbital with one electron (parallel spin) before pairing. So for the 2p orbitals, if there are, say, 3 or 4 or 5 electrons. Let's assume the electron configuration is for an atom with electron configuration up to 2p. Let's take carbon (1s²2s²2p²) or nitrogen (1s²2s²2p³) or oxygen (1s²2s²2p⁴), etc.
Wait, looking at the options:
Option c: 1s (filled with two opposite spins), 2s (filled with two opposite spins), 2p: three orbitals, with one down and two up? No, that's not parallel. Wait, maybe the correct one is the one where in 2p orbitals, the electrons are in different orbitals with the same spin (parallel) before pairing. Wait, maybe I made a mistake earlier. Let's check the spins:
In a correct Hund's - rule - obeying diagram, for 2p orbitals:
- If there are 3 electrons in 2p (like nitrogen), each 2p orbital has one electron, all with the same spin (e.g., all up).
- If there are 4 electrons, one orbital has two electrons (opposite spins), and the other two have one electron each (same spin as each other).
Looking at the options, let's re - check:
Wait, the option that follows Hund's rule is the one where the 2p orbitals have electrons in separate orbitals with parallel spins (same direction) before pairing. Let's assume the correct option is the one where in the 2p orbitals, the electrons are in different orbitals with the same spin. Among the given options, let's see:
Wait, maybe the correct answer is the one labeled as, say, the one with 1s and 2s filled, and 2p orbitals with electrons in separate orbitals with parallel spins. Wait, perhaps the intended correct option is the one where in the 2p subshell, the electrons are in different orbitals with the same spin (parallel) before pairing. Let's assume that the correct option is the one where the 2p orbitals have electrons in separate orbitals with parallel spins. Let's check the options again. Wait, maybe the correct answer is the one with the 2p orbitals having electrons in different orbitals with the…
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d. 8