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Question
question 27 (3 points)
rank these compounds in order of increasing boiling point: methoxymethane (ch₃och₃), ethanol (ch₃ch₂oh), and propane (ch₃ch₂ch₃). explain your answer
Brief Explanations
Boiling point depends on intermolecular forces (IMFs): stronger IMFs → higher boiling point.
- Propane ($\text{CH}_3\text{CH}_2\text{CH}_3$): Nonpolar, only weak London dispersion forces (LDFs).
- Methoxymethane ($\text{CH}_3\text{OCH}_3$): Polar (C-O bonds), so dipole-dipole forces (stronger than LDFs in similar-sized molecules).
- Ethanol ($\text{CH}_3\text{CH}_2\text{OH}$): Has an -OH group, allowing hydrogen bonding (strongest IMF here).
Thus, the order of increasing boiling point is propane < methoxymethane < ethanol.
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Propane ($\text{CH}_3\text{CH}_2\text{CH}_3$) < methoxymethane ($\text{CH}_3\text{OCH}_3$) < ethanol ($\text{CH}_3\text{CH}_2\text{OH}$)