QUESTION IMAGE
Question
- use the solubility rules to identify the precipitate in the reaction. aqueous solutions of potassium hydroxide and cobalt(iii) nitrate are mixed.
here are the solubility rules.
- alkali metal (li+, na+, k+, etc) and ammonium (nh4+) salts are generally soluble. exceptions include li2co3 and li3po4.
- nitrate (no3-) salts are generally soluble.
- silver (ag+) and lead (pb2+) salts are generally insoluble.
- halide (cl-, br-, and i-) salts are generally soluble. exceptions include pb2+, ag+, hg22+.
- carbonate (co32-), phosphate (po43-), and hydroxide (oh-) salts are generally insoluble.
- sulfate (so42-) salts are generally soluble. exceptions include caso4, srso4, baso4, pbso4, and ag2so4.
Step1: Write the reaction equation
The reaction between potassium hydroxide ($\ce{KOH}$) and cobalt(III) nitrate ($\ce{Co(NO_{3})_{3}}$) is a double - displacement reaction. The chemical equation is:
$$\ce{3KOH(aq) + Co(NO_{3})_{3}(aq)\xlongequal{}Co(OH)_{3}(s) + 3KNO_{3}(aq)}$$
Step2: Apply solubility rules to each product
- For $\ce{KNO_{3}}$: According to rule 2 (Nitrate ($\ce{NO_{3}^{-}}$) salts are generally soluble) and rule 1 (Alkali metal ($\ce{K^{+}}$) salts are generally soluble), $\ce{KNO_{3}}$ is soluble in water.
- For $\ce{Co(OH)_{3}}$: According to rule 5 (Hydroxide ($\ce{OH^{-}}$) salts are generally insoluble). Cobalt(III) ion ($\ce{Co^{3+}}$) is not an exception - making ion for hydroxide solubility. So $\ce{Co(OH)_{3}}$ is insoluble and will form a precipitate.
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The precipitate formed is $\ce{Co(OH)_{3}}$, so the correct option is $\ce{Co(OH)_{3}}$.