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Question
from these data,
mathrm{s}(\text { rhombic })+mathrm{o}_{2}(g)
ightarrow mathrm{so}_{2}(g) quad delta h_{mathrm{rxn}}^{circ}=-296.06 \frac{mathrm{kj}}{mathrm{mol}}
mathrm{s}(\text { monoclinic })+mathrm{o}_{2}(g)
ightarrow mathrm{so}_{2}(g) quad delta h_{mathrm{rxn}}^{circ}=-296.36 \frac{mathrm{kj}}{mathrm{mol}}
calculate the enthalpy change for the transformation:
mathrm{s}(\text { rhombic })
ightarrow mathrm{s}(\text { monoclinic })
(monoclinic and rhombic are different allotropic forms of elemental sulfur.)
round your answer to 2 significant digits.
\frac{mathrm{kj}}{mathrm{mol}}
Step1: Reverse the second reaction
Reverse: $\ce{SO2(g) -> S(monoclinic) + O2(g)}$, $\Delta H^\circ_{\text{rxn}} = +296.36\ \frac{\text{kJ}}{\text{mol}}$
Step2: Add to first reaction
First reaction: $\ce{S(rhombic) + O2(g) -> SO2(g)}$, $\Delta H^\circ_{\text{rxn}} = -296.06\ \frac{\text{kJ}}{\text{mol}}$
Sum: $\ce{S(rhombic) -> S(monoclinic)}$
$\Delta H = (-296.06 + 296.36)\ \frac{\text{kJ}}{\text{mol}} = 0.30\ \frac{\text{kJ}}{\text{mol}}$
Step3: Round to 2 sig figs
$0.30\ \frac{\text{kJ}}{\text{mol}}$
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$0.30\ \frac{\text{kJ}}{\text{mol}}$