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Question
question 14 (5 points)
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hydrogen cyanide has the chemical formula hcn. whats the formal charge on the n atom?
a) -2
b) +2
c) -1
d) 0
Step1: Recall formal charge formula
The formula for formal charge (FC) is \( FC = V - N - \frac{B}{2} \), where \( V \) is the number of valence electrons in the neutral atom, \( N \) is the number of non - bonding (lone pair) electrons, and \( B \) is the number of bonding electrons.
For nitrogen (\( N \)): The number of valence electrons in a neutral \( N \) atom, \( V = 5 \).
In the HCN molecule, the Lewis structure of HCN is \( H - C\equiv N \). For the \( N \) atom in \( H - C\equiv N \):
- The number of non - bonding electrons (\( N \)): In a triple bond between \( C \) and \( N \), the \( N \) atom has 1 lone pair (2 non - bonding electrons), so \( N = 2 \).
- The number of bonding electrons (\( B \)): In a triple bond, there are 6 bonding electrons, so \( B = 6 \).
Step2: Calculate formal charge
Substitute the values into the formal charge formula:
\( FC=5 - 2-\frac{6}{2} \)
First, calculate \( \frac{6}{2}=3 \). Then, \( 5 - 2-3=0 \).
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D) 0