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Question
measurements show that unknown compound x has the following composition:
write the empirical chemical formula of x.
Step1: Assume 100g of the compound
If we assume we have 100g of compound \(X\), then the mass of iron (\(Fe\)) is \(m_{Fe}=69.9g\) and the mass of oxygen (\(O\)) is \(m_{O} = 30.0g\).
Step2: Calculate the number of moles of each element
The molar mass of \(Fe\) is \(M_{Fe}=55.85g/mol\), and the molar mass of \(O\) is \(M_{O}=16.00g/mol\).
The number of moles of \(Fe\), \(n_{Fe}=\frac{m_{Fe}}{M_{Fe}}=\frac{69.9g}{55.85g/mol}\approx1.25mol\)
The number of moles of \(O\), \(n_{O}=\frac{m_{O}}{M_{O}}=\frac{30.0g}{16.00g/mol}=1.875mol\)
Step3: Find the mole - ratio
Divide each number of moles by the smaller number of moles. Here, \(n = 1.25mol\) (for \(Fe\))
For \(Fe\): \(\frac{n_{Fe}}{n}=\frac{1.25mol}{1.25mol}=1\)
For \(O\): \(\frac{n_{O}}{n}=\frac{1.875mol}{1.25mol}=1.5\)
Multiply each ratio by 2 to get whole - numbers.
For \(Fe\): \(1\times2 = 2\)
For \(O\): \(1.5\times2=3\)
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\(Fe_2O_3\)