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Question
gases are different from solids and liquids. in a sample of gas, the molecules are far apart. the gas molecules also move around slide with each other as well as with the walls of the container. these collisions generate pressure. the pressure of a gas can be measured in different units. one convenient unit of measure is called the atmosphere (atm) because it is based on atmospheric pressure. at sea level, the average pressure is 1 atm. as you get higher in altitude, the pressure steadily drops until you leave the atmosphere, where the pressure is very close to 0 atm.
the table below shows the different commonly used units of measuring gas pressure. use this table in the pressure unit conversions.
| unit | abbreviation | 1 atm equivalent |
|---|---|---|
| millimeters of mercury | mmhg | 760 mmhg |
| torr | torr | 760 torr |
| inches of mercury | in. hg | 29.9 in. hg |
| pounds per square inch (psi) | lb/in.² | 14.7 lb/in.² |
| pascal | pa | 101325 pa |
part c
high-pressure liquid chromatography (hplc) is a method used in chemistry and biochemistry to purify chemical substances. the pressures used in this procedure range from around 500 kilopascals (500,000 pa) to about 60,000 kpa (60,000,000 pa). it is often convenient to know the pressure in torr. if an hplc procedure is running at a pressure of 3.64×10⁸ pa, what is its running pressure in torr?
express the pressure numerically in torr.
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3.64×10⁸ pa =
torr
Step1: Find conversion factor
From the table, \(1\ \text{atm} = 760\ \text{torr}\) and \(1\ \text{atm} = 101325\ \text{Pa}\). So, the conversion factor from Pa to torr is \(\frac{760\ \text{torr}}{101325\ \text{Pa}}\).
Step2: Apply conversion
Given pressure \(P = 3.64\times 10^{8}\ \text{Pa}\). Multiply by the conversion factor:
\(P_{\text{torr}} = 3.64\times 10^{8}\ \text{Pa} \times \frac{760\ \text{torr}}{101325\ \text{Pa}}\)
First, calculate \(3.64\times 10^{8} \times \frac{760}{101325}\):
\(\frac{3.64\times 10^{8} \times 760}{101325} \approx \frac{2.7664\times 10^{11}}{101325} \approx 2.73\times 10^{6}\) (after simplifying the arithmetic).
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\(2.73\times 10^{6}\) (or more precisely, after exact calculation: \(3.64\times10^{8} \times \frac{760}{101325} = \frac{3.64\times760\times10^{8}}{101325}=\frac{2766.4\times10^{8}}{101325}=\frac{276640000000}{101325}\approx 2730000\) or \(2.73\times 10^{6}\) torr)