QUESTION IMAGE
Question
draw (on paper) a lewis structure for nh₄⁺ and answer the following questions based on your drawing. do not draw double bonds unless they are needed for the central atom to obey the octet rule.
- for the central nitrogen atom:
the number of lone pairs =
the number of single bonds =
the number of double bonds =
- the central nitrogen atom
a. obeys the octet rule.
b. has an incomplete octet.
c. has an expanded octet.
Sub - question 1
Step 1: Determine valence electrons of atoms
Nitrogen (\(N\)) has 5 valence electrons, and each hydrogen (\(H\)) has 1 valence electron. The ion is \(NH_4^+\), so we subtract 1 electron for the positive charge. Total valence electrons \(= 5+4\times1 - 1=8\).
Step 2: Draw Lewis structure and analyze bonds/lone pairs
In the Lewis structure of \(NH_4^+\), the central \(N\) atom is bonded to 4 \(H\) atoms with single bonds. Each single bond uses 2 electrons. The total number of electrons used in bonding is \(4\times2 = 8\), which matches the total valence electrons. So, the number of lone pairs on \(N\) is 0 (since all 8 electrons are in bonding), the number of single bonds is 4, and the number of double bonds is 0.
The octet rule states that atoms tend to have 8 valence electrons. The central \(N\) in \(NH_4^+\) has 4 single bonds (8 electrons in bonding), so it has a complete octet and obeys the octet rule. Option A is correct as it obeys the octet rule, option B is wrong (it has a complete octet), and option C is wrong (it does not have an expanded octet as it has 8 electrons around it).
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- The number of lone pairs \(=\boldsymbol{0}\)
- The number of single bonds \(=\boldsymbol{4}\)
- The number of double bonds \(=\boldsymbol{0}\)