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Question
19 ccc stability and change predict whether or not the substances in the table will sublime at stp. base your predictions only on the type of bond or intermolecular force holding the solid together. will it sublime? substance type of bond or intermolecular force sublime at stp? carbon dioxide (co₂) hydrogen fluoride (hf) calcium chloride (cacl₂) naphthalene (c₁₀h₈) iodine (i₂) sodium chloride (nacl) water (h₂o) 2 modeling ph
Step1: Identify bond/force for CO₂
CO₂ has weak London - dispersion forces. Low - boiling substances with weak intermolecular forces can sublime at STP.
Step2: Identify bond/force for HF
HF has hydrogen bonding. It has a relatively higher boiling point compared to substances with only London - dispersion forces, but can still sublime due to the relatively weak nature of hydrogen - bonding compared to ionic bonds.
Step3: Identify bond/force for CaCl₂
CaCl₂ has ionic bonds. Ionic compounds have high melting and boiling points and do not sublime at STP.
Step4: Identify bond/force for C₁₀H₈
Naphthalene has London - dispersion forces. It is a low - melting solid and can sublime at STP.
Step5: Identify bond/force for I₂
Iodine has London - dispersion forces. It can sublime at STP as it has relatively weak intermolecular forces.
Step6: Identify bond/force for NaCl
NaCl has ionic bonds. Ionic compounds do not sublime at STP due to strong ionic bonds.
Step7: Identify bond/force for H₂O
Water has hydrogen bonding. It does not sublime at STP under normal conditions as its hydrogen - bonding leads to a relatively high melting and boiling point range compared to substances that sublime at STP.
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| Substance | Type of Bond or Intermolecular Force | Sublime at STP? |
|---|---|---|
| Hydrogen fluoride (HF) | Hydrogen bonding | Yes |
| Calcium chloride (CaCl₂) | Ionic bonds | No |
| Naphthalene (C₁₀H₈) | London - dispersion forces | Yes |
| Iodine (I₂) | London - dispersion forces | Yes |
| Sodium chloride (NaCl) | Ionic bonds | No |
| Water (H₂O) | Hydrogen bonding | No |