QUESTION IMAGE
Question
- predict the molecular shape of cos (1 point) *
linear
bent
trigonal planar
trigonal pyramidal
tetrahedral
- predict the molecular shape of ph3 (1 point) *
linear
bent
trigonal planar
trigonal pyramidal
tetrahedral
Question 14 (COS Molecular Shape)
Step1: Determine Lewis Structure
COS has a structure similar to CO₂ but with a sulfur. Carbon is central, double - bonded to O and S. The Lewis structure is \(O = C = S\).
Step2: Calculate Electron Domains
The central C has 2 double bonds (each double bond is 1 electron domain for shape prediction, as we consider bonding groups). So there are 2 electron domains (both bonding, no lone pairs on C).
Step3: Determine Molecular Shape
For a central atom with 2 bonding domains and 0 lone pairs, the molecular shape is linear (based on VSEPR theory: electron domain geometry and molecular shape are linear for 2 bonding domains with no lone pairs).
Step1: Determine Lewis Structure
Phosphorus is central, bonded to 3 H atoms. Phosphorus has 5 valence electrons, 3 are used in bonding with H, so there is 1 lone pair on P. The Lewis structure is \(H_3P\) with a lone pair on P.
Step2: Calculate Electron Domains
The central P has 3 bonding domains (with H) and 1 lone pair, so total electron domains = 4.
Step3: Determine Molecular Shape
The electron domain geometry is tetrahedral, but the molecular shape (considering only bonding groups) is trigonal pyramidal (because of 1 lone pair and 3 bonding groups; the lone pair repels the bonding pairs, giving a trigonal pyramidal shape, similar to NH₃).
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A. Linear