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Question
describe five factors that affect the rate of chemical reactions.
Brief Explanations
- Concentration (or Pressure for Gases): Increasing the concentration of reactants (or pressure of gaseous reactants) increases the frequency of reactant particle collisions, thus increasing the reaction rate. For example, in the reaction $\ce{2H_{2} + O_{2} -> 2H_{2}O}$, higher $\ce{H_{2}}$ and $\ce{O_{2}}$ concentrations lead to more frequent collisions between $\ce{H_{2}}$ and $\ce{O_{2}}$ molecules.
- Temperature: Raising the temperature increases the kinetic energy of particles. This means particles move faster, collide more frequently, and a larger proportion of collisions have energy equal to or greater than the activation energy. For instance, reactions like the rusting of iron occur faster at higher temperatures.
- Surface Area (for Solids): Breaking a solid into smaller pieces (increasing its surface area) exposes more reactant particles to the other reactant. For example, powdered zinc reacts faster with hydrochloric acid than a zinc strip because the powder has a larger surface area, leading to more frequent collisions between zinc and $\ce{H^{+}}$ ions.
- Catalysts: A catalyst increases the reaction rate by providing an alternative reaction pathway with a lower activation energy. It does not get consumed in the reaction. For example, in the decomposition of hydrogen peroxide ($\ce{2H_{2}O_{2} -> 2H_{2}O + O_{2}}$), manganese dioxide ($\ce{MnO_{2}}$) acts as a catalyst to speed up the reaction.
- Nature of Reactants: The chemical properties of reactants (e.g., ionic vs. covalent bonds, reactivity of elements) affect the reaction rate. For example, alkali metals (like sodium) react very quickly with water because they are highly reactive, while noble metals (like gold) react very slowly or not at all with most substances under normal conditions.
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- Concentration (or Pressure for Gases): Increases collision frequency of reactant particles.
- Temperature: Increases particle kinetic energy, collision frequency, and effective collisions.
- Surface Area (for Solids): Exposes more reactant particles, increasing collision frequency.
- Catalysts: Lower activation energy via an alternative reaction pathway.
- Nature of Reactants: Depends on chemical properties (e.g., reactivity, bond type) of reactants.