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in the laboratory you are given the task of separating pb2+ and zn2+ io…

Question

in the laboratory you are given the task of separating pb2+ and zn2+ ions in aqueous solution.
for each reagent listed below indicate if it can be used to separate the ions. type \y\ for yes or
\ for no. if the reagent can be used to separate the ions, give the formula of the precipitate. if it cannot, type
o\

Explanation:

1. For NaCl:

  • When NaCl reacts with \(Pb^{2 +}\) and \(Zn^{2+}\) in aqueous solution:
  • The reaction with \(Pb^{2+}\) is \(Pb^{2+}+2Cl^{-}=PbCl_{2}\downarrow\) (since \(PbCl_{2}\) is insoluble in cold water, soluble in hot water).
  • The reaction with \(Zn^{2+}\) is \(Zn^{2+}+2Cl^{-}=ZnCl_{2}\) (\(ZnCl_{2}\) is soluble in water). So, it can be used to separate the ions.

2. For KOH:

  • When KOH reacts with \(Pb^{2 +}\) and \(Zn^{2+}\) in aqueous solution:
  • The reaction with \(Pb^{2+}\) is \(Pb^{2+}+2OH^{-}=Pb(OH)_{2}\downarrow\).
  • The reaction with \(Zn^{2+}\) is \(Zn^{2+}+2OH^{-}=Zn(OH)_{2}\downarrow\) (and \(Zn(OH)_{2}+2OH^{-}=ZnO_{2}^{2 -}+2H_{2}O\) in excess KOH, but initially both form precipitates, so it cannot be used to separate them simply).

3. For \(Na_{2}SO_{4}\):

  • When \(Na_{2}SO_{4}\) reacts with \(Pb^{2 +}\) and \(Zn^{2+}\) in aqueous solution:
  • The reaction with \(Pb^{2+}\) is \(Pb^{2+}+SO_{4}^{2 -}=PbSO_{4}\downarrow\).
  • The reaction with \(Zn^{2+}\) is \(Zn^{2+}+SO_{4}^{2 -}=ZnSO_{4}\) (\(ZnSO_{4}\) is soluble in water). So, it can be used to separate the ions.

Answer:

  1. Y, \(PbCl_{2}\)
  2. N
  3. Y, \(PbSO_{4}\)