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Question
what is the next atomic orbital in the series 1s, 2s, 2p, 3s, 3p?
3d
3f
2d
4s
According to the Aufbau principle, the order of filling atomic orbitals is based on the increasing energy of the orbitals. The general order is \(1s < 2s < 2p < 3s < 3p < 4s < 3d<4p\). After \(3p\), the next orbital to be filled is \(4s\). Orbital \(2d\) does not exist as for \(n = 2\), the possible values of \(l\) (azimuthal quantum number) are \(0\) (s - orbital) and \(1\) (p - orbital). For \(n=3\), after filling \(3p\), we first fill \(4s\) (lower energy) rather than \(3d\) (higher energy than \(4s\) in terms of Aufbau order). Orbital \(3f\) also does not exist as for \(n = 3\), the possible values of \(l\) are \(0\) (s), \(1\) (p) and \(2\) (d).
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4s