QUESTION IMAGE
Question
the table below lists information about some diatomic molecules or molecular ions. for each molecule in the table:
first, decide if the molecule is stable or not. then, if your answer to this question is \yes\:
- decide whether the molecule would be diamagnetic or paramagnetic.
- calculate the molecules bond order.
| molecule | stable? | diamagnetic or paramagnetic? | bond order |
|---|---|---|---|
| $be_2$ | yes <br> no | diamagnetic <br> paramagnetic | |
| $ne_2$ | yes <br> no | diamagnetic <br> paramagnetic |
Step1: Recall molecular - orbital theory
Molecular - orbital theory is used to determine stability, magnetic properties, and bond - order. The bond - order formula is $BO=\frac{1}{2}(N_b - N_a)$, where $N_b$ is the number of bonding electrons and $N_a$ is the number of antibonding electrons.
Step2: Analyze $B_2$
The electron - configuration of $B$ is $1s^22s^22p^1$. For $B_2$, the molecular - orbital configuration is $(\sigma_{1s})^2(\sigma_{1s}^*)^2(\sigma_{2s})^2(\sigma_{2s}^*)^2(\pi_{2p_x})^1(\pi_{2p_y})^1$. $N_b = 6$, $N_a = 4$. $BO=\frac{1}{2}(6 - 4)=1$. Since $BO>0$, $B_2$ is stable. It has unpaired electrons, so it is paramagnetic.
Step3: Analyze $Be_2$
The electron - configuration of $Be$ is $1s^22s^2$. For $Be_2$, the molecular - orbital configuration is $(\sigma_{1s})^2(\sigma_{1s}^*)^2(\sigma_{2s})^2(\sigma_{2s}^*)^2$. $N_b = 4$, $N_a = 4$. $BO=\frac{1}{2}(4 - 4)=0$. Since $BO = 0$, $Be_2$ is unstable.
Step4: Analyze $Ne_2$
The electron - configuration of $Ne$ is $1s^22s^22p^6$. For $Ne_2$, the molecular - orbital configuration has a large number of antibonding electrons. $N_b = 8$, $N_a = 8$. $BO=\frac{1}{2}(8 - 8)=0$. Since $BO = 0$, $Ne_2$ is unstable.
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| molecule | stable? | diamagnetic or paramagnetic? | bond order |
|---|---|---|---|
| $Be_2$ | no | N/A (unstable) | 0 |
| $Ne_2$ | no | N/A (unstable) | 0 |