QUESTION IMAGE
Question
study the following sketch of a molecular orbital (mo) in a homonuclear diatomic molecule. this mo was formed by combining one 2p atomic orbital from each atom. the dark dots in this sketch are the nuclei. now use the sketch to complete the table below. write the symbol for this mo. is this a bonding or antibonding mo? what is the energy of this mo, compared to the energy of a 2p orbital on one of the separate atoms?
Step1: Identify molecular - orbital symbol
When one 2p atomic orbital from each atom combines to form an anti - bonding molecular orbital, the symbol is $\pi^*$.
Step2: Determine bonding or anti - bonding
The $\pi^*$ orbital is an anti - bonding orbital. In anti - bonding orbitals, there is a node between the nuclei, which is consistent with the nature of the orbital formed here.
Step3: Compare energy
Anti - bonding molecular orbitals have higher energy than the atomic orbitals from which they are formed. So, the energy of this $\pi^*$ MO is higher than the energy of a 2p orbital on one of the separate atoms.
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| Property | Answer |
|---|---|
| Bonding or anti - bonding | anti - bonding |
| Energy compared to 2p orbital | higher |