QUESTION IMAGE
Question
sch4u
structure and
properties of matter
assignment
- complete the table below by providing a set of quantum numbers for the last four
electrons in an phosphorus atom. 4
Step1: Determine the spin quantum number for electron 3
According to the Pauli exclusion principle, electrons in the same orbital have opposite spins. For electron 3, since it is in a \(p\) orbital (\(l = 1\)), and considering the Aufbau principle and Hund's rule, the spin quantum number \(m_s=+\frac{1}{2}\)
Step2: Determine the spin quantum number for electron 4
For electron 4, also in a \(p\) orbital (\(l = 1\)). Since electrons in different \(p\) - orbital (with different \(m_l\)) follow Hund's rule (parallel spins first), and assuming the previous spin for electron 3 is \(+\frac{1}{2}\), the spin quantum number \(m_s =+\frac{1}{2}\)
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| e- | Principle quantum number | Orbital Shape quantum numbers | Magnetic quantum number | Spin quantum number |
|---|---|---|---|---|
| 2 | 3 | 0 | 0 | \(-\frac{1}{2}\) |
| 3 | 3 | 1 | - 1 | \(+\frac{1}{2}\) |
| 4 | 3 | 1 | 0 | \(+\frac{1}{2}\) |