QUESTION IMAGE
Question
question 1 (0.0862 points)
how many valence electrons are in the nitrite ion?
22
18
26
17
question 2 (0.0862 points)
choose the pair of names and formulas that do not match.
copper(ii) nitrite: cu(no₂)₂
copper(ii) nitride: cu₃n₂
copper(ii) nitrate: cuno₃
copper(ii) nitrate: cu(no₃)₂
Question 1
Step1: Determine the formula of nitrite ion
The nitrite ion is $\ce{NO2^-}$.
Step2: Calculate valence electrons for each atom
- Nitrogen (N) is in group 15, so it has 5 valence electrons.
- Oxygen (O) is in group 16, so each O has 6 valence electrons. There are 2 O atoms, so total for O: $2\times6 = 12$.
- The ion has a -1 charge, which means it has gained 1 electron, so we add 1.
Step3: Sum the valence electrons
Total valence electrons = valence electrons of N + valence electrons of O + charge electrons.
So, $5 + 12 + 1 = 18$.
To determine the mismatched pair, we analyze the formulas based on ionic charges:
- Copper(II) has a charge of +2 ($\ce{Cu^{2+}}$).
- Nitrite ion is $\ce{NO2^-}$, so for copper(II) nitrite: $\ce{Cu(NO2)2}$ (since $2\times(+2) + 2\times(-1) = 0$) – matches.
- Nitride ion is $\ce{N^{3-}}$. For copper(II) nitride, the formula should balance charges: $3\ce{Cu^{2+}}$ and $2\ce{N^{3-}}$ give $\ce{Cu3N2}$ (since $3\times(+2) + 2\times(-3) = 0$) – matches.
- Nitrate ion is $\ce{NO3^-}$. For copper(II) nitrate, the formula should be $\ce{Cu(NO3)2}$ (since $+2 + 2\times(-1) = 0$ for $\ce{Cu^{2+}}$ and $\ce{NO3^-}$). The option "Copper(II) nitrate: $\ce{CuNO3}$" has an incorrect formula (charge imbalance: $+2 + (-1) = +1
eq 0$), while $\ce{Cu(NO3)2}$ is correct. So the mismatched pair is "Copper(II) nitrate: $\ce{CuNO3}$".
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