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Question
in this lab, you will determine the vapour pressure (p) of water at various temperatures and use this data to find its enthalpy of vaporization ($\delta_{vap}h$).
more generally, for an unknown liquid: if a plot of $\ln p$ vs. $1/t$ gives a slope of -3105 k, what is its $\delta_{vap}h$ in kj/mol? do not worry about how realistic the value is. assume $r = 8.314 j mol^{-1}k^{-1}$.
Step1: Recall the Clausius - Clapeyron equation
The Clausius - Clapeyron equation in the form of a linear equation \(y = mx + c\) for \(\ln P\) vs. \(\frac{1}{T}\) is \(\ln P=-\frac{\Delta_{vap}H}{R}\times\frac{1}{T}+C\). Here, the slope \(m =-\frac{\Delta_{vap}H}{R}\).
Step2: Solve for \(\Delta_{vap}H\)
Given \(m=- 3105\space K\) and \(R = 8.314\space J\space mol^{-1}\space K^{-1}\). From \(m =-\frac{\Delta_{vap}H}{R}\), we can solve for \(\Delta_{vap}H\). Rearranging the formula gives \(\Delta_{vap}H=-m\times R\).
Substitute the values: \(\Delta_{vap}H=-(-3105\space K)\times8.314\space J\space mol^{-1}\space K^{-1}\)
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\(25.8\space kJ/mol\)