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Question
- explain how ionic compounds with polyatomic ions are both ionic and covalent in terms of their bonding.
Ionic compounds with polyatomic ions have ionic bonds between the polyatomic ion (as a whole) and the other ion (cation or anion). Within the polyatomic ion, there are covalent bonds. For example, in $\ce{NaNO3}$, the bond between $\ce{Na+}$ and $\ce{NO3-}$ is ionic. Inside the $\ce{NO3-}$ ion, the bonds between $\ce{N}$ and $\ce{O}$ atoms are covalent.
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Ionic compounds with polyatomic ions have ionic bonds between the polyatomic ion (as a whole) and the other ion (cation or anion). Within the polyatomic ion, there are covalent bonds. For example, in $\ce{NaNO3}$, the bond between $\ce{Na+}$ and $\ce{NO3-}$ is ionic. Inside the $\ce{NO3-}$ ion, the bonds between $\ce{N}$ and $\ce{O}$ atoms are covalent.